{2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3 P,C 1,P′}iodidonickel(II)
نویسندگان
چکیده
In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis-[(diphenyl-phosphan-yl)-oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P-Ni-P angle of 164.20 (2)° and the P-Ni-C angles of 82.09 (6) and 82.11 (6)°. The rather short Ni-C bond length [1.890 (2) Å] is anti-cipated in light of the much stronger trans influence of the aryl moiety compared to the iodide ligand. The P-bound phenyl rings adopt different orientations to minimize steric repulsion among themselves.
منابع مشابه
{2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ3 P,C 1,P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II)
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